The hydrogen economy has received increasing attention recently. Common reasons cited for investigating hydrogen energy options are improved energy security, reduced environmental impacts, and its contribution to a transition to sustainable energy sources. In anticipation of these benefits, national and local initiatives have been launched in the United States, creating pilot “roadmaps” and technology partnerships to explore hydrogen economy platforms. Although hydrogen can provide several positive improvements over a carbon- or uranium-based energy system, several problems are (...) also likely. As well, competitive technologies (e.g., hybrid vehicles) may offer comparatively greater economic and/or environmental advantages. Before policies to advance a hydrogen energy economy proceed, it is vital that all aspects of hydrogen be compared with other available alternatives. Important questions to ask in this regard are whether a hydrogen economy can fulfill key energy needs and whether there are appropriate roles for hydrogen to play in a sustainable energy future. (shrink)

Hydrogen is a very important industrial gas in chemical processes. It is very volatile; therefore, it can escape from the process units and its mass balance is not always correct. In many industrial processes where hydrogen is reacted, kinetics are often related to hydrogen pressure. The right thermodynamic properties of hydrogen can be found for a process simulation and optimization; they can be estimated by the Grayson-Streed model. In the case studied, a methanol plant with a (...) capacity of 150,000 tons/year, the flow rate of hydrogen (H2) can be optimized using nonlinear programming, but good estimates of thermodynamic properties of hydrogen had to be found. In the case study, the model is in relatively good agreement with experimental measurements in the existing methanol production plant. An additional flow rate of hydrogen can increase the methanol production by 1.2%. Total potential profit increase of the additional methanol production was estimated to be 30 kEUR/a (or 103 euros/year). (shrink)

The hydrogen economy is a technological bluff in its implied assurance that, despite the accelerating pace at which we are depleting the remaining half of our fossil fuels, our energy future is secure. Elementary thermodynamic considerations are developed to show that a hydrogen economy is about as feasible as a perpetual motion machine. Hydrogen is not an energy source but an energy carrier, and when produced renewably, it is an energy carrier to the second degree, with electricity (...) being the energy carrier to the first degree. As such, it greatly elongates the chain of energy transformations required to deliver a desired service from a primary source of energy. There will undoubtedly be applications in which hydrogen may be essential, but they will be limited because the services it delivers will come at a substantial energy premium. (shrink)

Hydrogen has the potential to become a primary energy source for transportation and heat generation. It can also be used for sustainable and long-term energy storage and transport and could offer an attractive solution to address energy insecurity concerns during the net zero transition, mainly if hydrogen can be produced pollution-free. Notwithstanding the promises of green hydrogen, the introduction thereof in a country’s energy mix, especially in countries with no specific regulatory frameworks on hydrogen production, poses (...) various challenges. In addition to meeting capital requirements, since most existing regulatory frameworks do not expressly envisage green hydrogen production, introducing green hydrogen projects in many countries will require substantial and apposite policy measures to accommodate hydrogen production. This chapter examines the role that hydrogen can play in achieving net zero. It then discusses the legal barriers to introducing green hydrogen in the energy mix before discussing the policy considerations that may guide in addressing these barriers. (shrink)

The history of the hydrogen bond provides a good example of the of an important chemical concept. It illustrates the interplay between empirical and theoretical approaches to the problem of delimiting what has proved to be quite an elusive notion, with chemists whittling away at the particular sorts of case with a view to obtaining a precise, unitary concept. Even though there is a return to a more theoretically inspired notion in more recent research, empirical characterisations remain a feature (...) of the report of a Task Group recently set up by the IUPAC to reconsider the definition of the hydrogen bond, and this situation—by no means unusual for chemical concepts and principles—is unlikely to change in the foreseeable future. These developments are reviewed in this paper, which includes an extended discussion of the enormous significance hydrogen bonding has for the philosopher’s standard example of a “natural kind”, water. There is little to suggest a reduction to what philosophers of physics are pleased to call fundamental principles, and the details raise further questions about what essentialists could possibly have in mind when talking about the microscopic essence of water. (shrink)

Hydrogen is troublesome in any periodic table classification. This being so it may as well be placed in a position that confers desirable attributes to the arrangement of the elements, while notionally recognising its lineage to the group 1 alkali metals and the group 17 halogens. Since the noble gases bridge the halogens and the alkali metals, and hydrogen encompasses the transition from the alkali metals to the halogens, there is more to the idea of hydrogen over (...) helium. (Meyer 1870, p. 357) (Proust 1927, p. 559). (shrink)

(1983). Hydrogen production for ballooning during the French Revolution: An early example of chemical process development. Annals of Science: Vol. 40, No. 6, pp. 531-558.

Relatively few thinkers have attempted to develop a systematic ‘ethics of expertise’ (EOE) that can guide scientists and other technical experts in providing information to the public. This paper argues that the prima facie duty to disseminate information in a manner that does not damage the self-determination of decision makers could fruitfully serve as one of the core principles of an EOE. Moreover, this duty can be fleshed out in promising ways by drawing on the concept of informed consent, which (...) guides medical clinicians in preserving the self-determination of their patients. The paper applies the resulting ethical framework to recent policy discussions about hydrogen fuel-cell (HFC) vehicles, both because they have received a good deal of research funding and because their merits have been hotly debated. It concludes that technical experts providing information about HFC vehicles should be especially cognizant of three issues: (1) important alternatives to hydrogen technology that need to be addressed, (2) major false beliefs that should be prevented or corrected, and (3) significant framing effects that could influence the recipients of information. (shrink)

Interest in a hydrogen economy has grown significantly in the past decade. However, the success of old technologies that are being re-engineered to work on hydrogen, as well as the creation of new hydrogenbased technologies, hinges upon public interest in and demand for such technologies. With increasing investments in the research and development of hydrogen technologies, there exists a need to monitor public attitudes toward hydrogen to ensure its success as an alternative energy carrier. To address (...) this need, two surveys were conducted. The results of the first survey give insights about how colored information influences the public acceptance of hydrogen, and the results of the second survey elucidate what trade-offs the public is willing to accept during the transition to a hydrogen economy. Furthermore, the research highlights how hydrogen knowledge and acceptance differ among age, education, and gender groups. (shrink)

Significant research, funding and advocacy by government and industry in favour of hydrogen technologies saw investment in Australia almost double between 2021 and 2022 to A$230–303 billion. However, in late 2023, Australia still had no hydrogen producing facilities, while renewable energy contributed 35.9% of electricity generation in 2022. Contrast this support for hydrogen with Bruce Pascoe’s book Dark Emu (2014) which presents material on Australia’s First Nations people, whose sustainable agriculture and aquaculture activities were evident before British (...) colonisation. Pascoe’s book proffers a need for reflection on the use of natural resources. The need for respect raises the energy justice concept as the push for hydrogen gains traction. This chapter uses a targeted desktop review of the literature and the frame of energy justice theory, including its tenets of recognition, restorative, distributive and cosmopolitan justice, to query whether large-scale hydrogen production is a reasonable path for a just transition. (shrink)

The consequences of a generalized Dirac equation are discussed for the energy levels of the hydrogen atom. Apart from the usual generalizations of the Dirac equation by adding new interaction terms, we generalize the anticommutation rule of the Dirac matrices, which leads to spin-dependent propagation properties. Such a theory can be looked at as a model theory for testing Lorentz invariance or as an outcome of pregeometric dynamical induction schemes for space-time structure.For special examples of generalized Dirac matrices including (...) perturbation terms with respect to the SRT Dirac matrices, we derive the energy level of the hydrogen atom and find a hyperfine splitting due to these perturbations. A comparison of this additional splitting with Lamb shift measurements gives us upper limits for possible perturbations, which turn out to be of measurable magnitude. Spin precession experiments give much more restrictive limits. So, it turns out that the hydrogen atom is not such a sensitive indicator for the Lorentz invariance as widely believed. (shrink)

An economically viable and environmental friendly method of generating hydrogen for fuel cells is by the reaction of certain metals with steam, called metalsteam reforming (MSR). This technique does not generate any toxic by-products nor contributes to the undesirable greenhouse effect. From the standpoint of favorable thermodynamics, total environmental benignity, and attractive economics, iron appears to be the metal of choice for such a process. An inexpensive source of iron for the MSR is the steel industry's mill-scale waste via (...) hydrogen and carbothermic reduction, both of which are energy-intensive processes. These have been eliminated by a novel, solution-based room temperature technique producing nanoscale iron, thus obviating the sintering of iron or iron oxide and deactivation during the cyclic operation of MSR. Some preliminary results are presented of an investigation aimed at converting the mill-scale waste into nanoscale iron, which was subsequently used in generating hydrogen for proton exchange membrane fuel cells. (shrink)

SummaryFrom a survey of the literature it appears that many inorganic oxidations yield hydrogen while inorganic reductions may yield oxygen.As many organisms are known to be able to utilize hydrogen as a source of energy in their carbon dioxide assimilation the generation of hydrogen in the inorganic milieu may be the unifying principle in the metabolism of the chemo-autotroph.Such is in keeping with the Unitarian theory of biochemistry proposed by the late Professor A. J.Kluyver in 1925.

In a recent paper the authors studied numerically the hydrogen ground state in stochastic electrodynamics within the the non-relativistic approximation. In quantum theory the leading non-relativistic corrections to the ground state energy dominate the Lamb shift related to the photon cloud that should cause the quantum-like behaviour of SED. The present work takes these corrections into account in the numerical modelling. It is found that they have little effect; the self-ionisation that occurs without them remains present. It is speculated (...) that the point-charge approximation for the electron is the cause of the failure. (shrink)

The symmetries of the humble hydrogen atom illustrate the importance of graded modal reasoning in science. By seemingly functioning as meta-laws, these symmetry principles create pressure for any philosophical account of nomological reasoning to accommodate graded modal claims. Marc Lange’s account of laws elegantly captures the hierarchical structure of reasoning in terms of laws and meta-laws. However, Lange’s account requires commitment to primitive counterfactuals in reality. To avoid this commitment, I develop an empiricist-friendly, expressivist reconstrual of Lange’s framework. Applying (...) this to scientists’ claims about the hydrogen atom, I show one way empiricists can vindicate graded modal claims while avoiding substantial metaphysical commitments. (shrink)

The placement of hydrogen in the periodic table has unique implications for fundamental questions of chemical behavior. Recent arguments in favor of placing hydrogen either separately at the top of the table or as a member of the carbon family are shown to have serious defects. A Coulombic model, in which all compounds of hydrogen are treated as hydrides, places hydrogen exclusively as the first member of the halogen family and forms the basis for reconsideration of (...) fundamental concepts in bonding and structures. The model provides excellent descriptive and predictive ability for structures and reactivities of a wide range of substances. (shrink)

Several attempts have recently been made to point to ‘the proper place’ for hydrogen in the Periodic Table of the elements. There are altogether five different types of arguments that lead to the following conclusions: hydrogen should be placed in group 1, above lithium; hydrogen should be placed in group 17, above fluorine; hydrogen is to be placed in group 14, above carbon; hydrogen should be positioned above both lithium and fluorine and hydrogen should (...) be treated as a stand-alone element, in the center of the Periodic Table. Although all proposals are based on arguments, not all of them sound equally convincing. An attempt is made, after critical reexamination of the arguments offered, to hopefully point to the best possible choice for the position of hydrogen. A few words are also mentioned on the structure of the Periodic Table and the attempts to reorganize it. (shrink)

Hydrogen energy systems are being developed to replace fossil fuels–based systems for transportation and stationary application. One of the challenges facing the widespread adoption of hydrogen as an energy vector is the lack of an efficient, economical, and sustainable method of hydrogen production. In the short term, hydrogen produced from fossil fuels will facilitate a transition to the hydrogen economy. In the long term, renewable hydrogen production methods will have to be adopted as resources (...) become scarce, causing the price of fossil fuels to rise. In this work, a number of methods have been considered for the renewable production of solar hydrogen, and thermochemical sulphur-iodine cycles proved to be the most promising. The sulphur-iodine cycles have the highest efficiencies and use widely available reactants with relatively straightforward reaction mechanisms, which make them the most economical and technically feasible option for renewable hydrogen production. (shrink)

Until the 1860s, science in Russia was principally conducted in Latin, French, and German. In the years leading up to and following the creation of the Russian Chemical Society in 1868, Russian chemists – treated in this article as both a representative sample of Russian scientists and also practitioners of the flagship science of the period – debated both the merits of developing a nomenclature that would enable Russian to “hold” modern inorganic and organic chemistry, and the practicability of doing (...) so. The article explores debates over whether Russian syntax could be adapted to represent chemical compounds according to emerging western conventions or in a sui generis manner, as well as the struggles of Russian scientists to use French and German to communicate with their foreign counterparts, arguing that the details of these debates highlight both the fruitfulness and the limits of using “standardization” as a framework for linguistic codification. (shrink)

Niels Bohr’s model of the hydrogen atom is widely cited as an example of an inconsistent scientific theory because of its reliance on classical electrodynamics together with assumptions about interactions between matter and electromagnetic radiation that could not be reconciled with CED. This view of Bohr’s model is controversial, but we believe a recently proposed approach to reasoning with inconsistent commitments offers a promising formal reading of how Bohr’s model worked. In this paper we present this new way of (...) reasoning with inconsistent commitments and compare it with other approaches before applying it to Bohr’s model and offering some suggestions for how it might be extended to account for subsequent developments in old quantum theory. (shrink)

Complex superpositions of degenerate hydrogen wavefunctions for the n th energy level can possess zero lines (phase singularities) in the form of knots and links. A recipe is given for constructing any torus knot. The simplest cases are constructed explicitly: the elementary link, requiring n≥6, and the trefoil knot, requiring n≥7. The knots are threaded by multistranded twisted chains of zeros. Some speculations about knots in general complex quantum energy eigenfunctions are presented.

The hydrogen market in the world today is capable ovule and empirical evidence on activity of patents in fuel cells and hydrogen production is limited so far. Patent applications in zero-emission mobility in the aspect of fuel cells include: DAFC/dmfc&dmfc, PEMFC, SOFC, AFC, PAFC. As for the patents relating to the hydrogen production, they concern low carbon, electrolysis and inorganic. The purpose of the study was to investigate certain aspects of the activity of patents in fuel cells (...) and hydrogen production in the context of passenger car fleet in the Visegrad group (V4) countries and to explore the relationship between patent registrations and GDP per capita in V4. The research area relates to the answer to the question of whether a country’s involvement in zero-emission patent activity (patents in fuel cells and hydrogen production) could contribute to the renewal of the country’s passenger car fleet. The theses were formulated as follows: 1) activity of patents in fuel cells and hydrogen production in the V4 countries doesn’t depend on the car fleet in these countries, 2) the level of GDP per capita in the V4 countries is not followed by the number of patents registrations in hydrogen technology, 3) the highest patent activity in fuel cells and hydrogen production doesn’t mean that the car fleet in these country will be zero-emission in coming years. The method used in this article is a comparative analysis, but also the relationships between patent registrations, GDP per capita and passenger car fleet in V4 are considered. (shrink)

Summary The balloon mania between 1783 and 1785 put an extraordinary strain on the Paris Academy of Sciences, threatening its status as the highest tribunal of European science. Faced with repeated royal directives and public frenzy, the Academy manoeuvred carefully to steer the research toward the hydrogen balloon and thereby to maintain its scientific superiority. Antoine-Laurent Lavoisier seized this moment when the promise of ?the empire of airs? brought science to the centre of public attention to push his theoretical (...) reform for chemistry. He utilized the established protocol of the Academy and the resources of the Republic of Letters to broadly publicize his first decomposition of water in April 1784. Once he attained the publicity and the balloon fever began to cool, he staged a much more elaborate experiment for the experts in February 1785. Although this second, large-scale experiment cost much expense and effort, Lavoisier never published a full account. The differential care given to the two experiments can only be understood in their divergent rhetorical contexts. The written accounts in 1784 addressed the court of public opinion, while the exclusive performance in 1785 aimed at the court of experts to inaugurate the collaborative phase of the Chemical Revolution. (shrink)

In this new edition of his pioneering book "Tomorrow's Energy," Peter Hoffmann makes the case for hydrogen as the cornerstone of a new energy economy.

Summary The balloon mania between 1783 and 1785 put an extraordinary strain on the Paris Academy of Sciences, threatening its status as the highest tribunal of European science. Faced with repeated royal directives and public frenzy, the Academy manoeuvred carefully to steer the research toward the hydrogen balloon and thereby to maintain its scientific superiority. Antoine-Laurent Lavoisier seized this moment when the promise of ‘the empire of airs’ brought science to the centre of public attention to push his theoretical (...) reform for chemistry. He utilized the established protocol of the Academy and the resources of the Republic of Letters to broadly publicize his first decomposition of water in April 1784. Once he attained the publicity and the balloon fever began to cool, he staged a much more elaborate experiment for the experts in February 1785. Although this second, large-scale experiment cost much expense and effort, Lavoisier never published a full account. The differential care given to the two experiments can only be understood in their divergent rhetorical contexts. The written accounts in 1784 addressed the court of public opinion, while the exclusive performance in 1785 aimed at the court of experts to inaugurate the collaborative phase of the Chemical Revolution. (shrink)

The status of the chemical bond has long been a controversial issue with the increasing distance between quantum chemists’ theoretical understanding of molecular stability and the ideas of experimental chemists. Some aspects of the development of the concept of a hydrogen bond are discussed with a view to assessing its import on the general question.

An existing industrial hydrogen generation and distribution infrastructure is described, and a number of large-scale investment projects are outlined. All of these projects have the potential to generate significant volumes of low-cost, low-carbon hydrogen. The technologies concerned range from gasification of coal with carbon capture and storage to gasification of a range of biomass streams. These biomass streams derive in turn from the supply chains that feed large liquid biofuel production plants—some operational and the others under construction. Having (...) described how such developments are coming together in a particular location to allow accelerated movement toward a hydrogen economy, this article explores the conditions under which similar acceleration could be seen in other locations. (shrink)

We treat the classical dynamics of the hydrogen atom in perpendicular electric and magnetic fields as a celestial mechanics problem. By expressing the Hamiltonian in appropriate action–angle variables, we separate the different time scales of the motion. The method of averaging then allows us to reduce the system to two degrees of freedom, and to classify the most important periodic orbits.

The predictions by the Department of Energy indicate the maximum of the rate of supply of oil will be reached around 2021, but this neglects the effect of the rapid growth of China and India. It will be necessary to use coal, natural gas, nuclear power, or renewables to supplement, and, after 2021, to replace oil. If coal is used, it can be reacted with steam to produce H2, the burning of which produces only water. If nuclear power is developed, (...) the 30% of nuclear energy at present wasted can be used to produce H2. Renewables are sporadic and need hydrogen as a storage means and for transmission. (shrink)

The operator structures for the constants of the motion of the relativistic hydrogen atom are examined. ThoughJ 3 andJ · J are constants of the motion,J is not. Its replacement, $\tilde {\rm K}$ , is shown to emerge rather naturally in transforming the equation to spherical coordinates. The separation of variables is presented in hypercomplex number form. This leads to some interesting suggestions regarding the matter/antimatter operator for the Dirac equation.

The theory of the 2S 1/2-2P 1/2 Lamb shift of hydrogen is reviewed and compared to experiment. Recent corrections from radiative recoil of order α(Zα)5 m 2 /M and pure recoil of order (Zα) 6 m 2 /M are discussed. Contributions of order α 2 (Zα) 5 m have been calculated from certain classes of diagrams. These are described while other as yet uncalculated terms are mentioned. The largest error in the theory is due to the uncertain measured value (...) of the proton electromagnetic radius. (shrink)

We review some of the progress made in the past 27 years in understanding the group theoretic and path integral aspects of the hydrogen atom. The group theoretic development was triggered by A. O. Barut who suggested to me the search for a dynamical group larger than SO(4). In this way he became indirectly responsible also for important recent path integral developments.

It is usually claimed that the Laguerre polynomials were popularized by Schrödinger when creating wave mechanics; however, we show that he did not immediately identify them in studying the hydrogen atom. In the case of relativistic Dirac equations for an electron in a Coulomb field, Dirac gave only approximations, Gordon and Darwin gave exact solutions, and Pidduck first explicitly and elegantly introduced the Laguerre polynomials, an approach neglected by most modern treatises and articles. That Laguerre polynomials were not very (...) popular before their use in quantum mechanics, probably because they had been little used in classical mathematical physics, is confirmed by the fact that, as we show, they had been rediscovered independently several times during the nineteenth century, in published or unpublished studies of Abel, Murphy, Chebyshev, and Laguerre. (shrink)

Asim Barut once,en passant, asked the question “For what transitions of the hydrogen atom do the spectral lines coincide”? It is a pleasure for us to give the answer in this paper.

This paper develops a structural and ontological account of development understood as the persistence of an unresolved remainder. A structure develops only insofar as it sustains a locus of continuation—a growth front—through which further extension remains possible. When all relevant degrees of freedom are internally compensated, development is suspended and the structure enters a regime of local closure. The analysis introduces the notion of an odd remainder as a structural operator distinguishing regimes that demand continuation from those that admit closure. (...) This distinction is traced across domains, including biological growth and atomic organization, not as metaphor but as a regime-level invariant. Atomic hydrogen and helium are treated as limiting structural cases: hydrogen exemplifies processual unity sustained by intrinsic openness, while helium exemplifies configurational unity achieved through local closure. The aim of the paper is ontological and methodological rather than predictive. No new physical mechanisms are proposed. Instead, the work offers criteria for distinguishing structural principles from descriptive artifacts by tracking transitions between continuation, closure, and metastability across domains. (shrink)

In this article, a number of future energy visions, especially those basing the energy systems on hydrogen, are discussed. Some often missing comparisons between alternatives, from a sustainability perspective, are identified and then performed for energy storage, energy transportation, and energy use in vehicles. It is shown that it is important to be aware of the losses implied by production, packaging, distribution, storage, and end-use of hydrogen when suggesting a “hydrogen economy.” It is also shown that for (...) stationary electric energy storage, fuel cell electrolyzers could be feasible. Zero-tailpipeemission vehicles are compared. The battery electric vehicle has the highest electrical efficiency, but other requirements imply that plug-in hybrids or fuel cell hybrids might be a better option in some types of vehicles. Finally, a simplified example is applied to the overall results and used to discuss the needs and nature of an energy system based on intermittent energy sources. (shrink)